One highlight of the show is a special performance by reigning CMA Entertainer of the Year Taylor Swift, who premiered her new single "Mine" for her fans at a top-secret private event in Nashville during CMA Music Festival. The song is the first single from her upcoming album Speak Now, in stores Oct. 25.

The special will also feature performances by Jason Aldean, Billy Currington, Alan Jackson, Kid Rock, Lady Antebellum, Miranda Lambert, Martina McBride, Reba McEntire, McGraw, Justin Moore, Brad Paisley, Kellie Pickler, Rascal Flatts, Darius Rucker, Blake Shelton with Trace Adkins, Josh Turner, Carrie Underwood, Keith Urban, and Zac Brown Band filmed in front of a sold-out audience in June during CMA Music Festival in Nashville at LP Field, home of the NFL's Tennessee Titans

Viewers will also enjoy two collaborative performances filmed at Fuel Bar & Nightclub in Downtown Nashville in front of a jam-packed crowd of Festival attendees. First, Dierks Bentley and Jamey Johnson join Lambert to sing "Bad Angel," a track from Bentley's current CD, Up on the Ridge. Later, Uncle Kracker and Kid Rock perform "Good To Be Me," featured on Uncle Kracker's recently released CD, Happy Hour: The South River Road Sessions.

Offering an insider's glimpse at the Festival, Lady Antebellum allowed cameras to follow them for a day at the event. Viewers will see the reigning CMA Vocal Group of the Year perform at their fan club party, interact with Festival attendees during an unplanned appearance in the Fan Fair Exhibit Hall, and more.